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- James Miller 1819-1825
- George Izard 1825-1828
- Robert Crittenden (acting) 1828-1829
- John Pope (Democrat) 1829-1835
- William S. Fulton (Democrat) 1835-1836
- William S. Fulton (Democrat) 1836
- James Sevier Conway (Democrat) 1836-1840
- Archibald Yell (Democrat) 1840-1844
- Samuel Adams (Democrat, acting) 1844
- Thomas Stevenson Drew (Democrat) 1844-1849
- Richard C. Byrd (Democrat, acting) 1849
- John Selden Roane (Democrat) 1849-1852
- Elias Nelson Conway (Democrat) 1852-1860
- Henry Massey Rector (Democrat) 1860-1862
- Harris Flanagin (Democrat) 1862-1864
- Isaac Murphy (Unionist) 1864-1868
- Powell Clayton (Republican) 1868-1871
- Ozra Amander Hadley (Republican, acting) 1871-1873
- Elisha Baxter (Republican) 1873-1874
- Augustus Hill Garland[?] (Democrat) 1874-1877
- William Read Miller (Democrat) 1877-1881
- Thomas James Churchill (Democrat) 1881-1883
- James Henderson Berry (Democrat) 1883-1885
- Simon Pollard Hughes, Jr. (Democrat) 1885-1889
- James Philipp Eagle (Democrat) 1889-1893
- William Meade Fishback (Democrat) 1893-1895
- James Paul Clarke (Democrat) 1895-1897
- Daniel Webster Jones (Democrat) 1897-1901
- Jefferson Davis (Democrat) 1901-1907
- John Sebastian Little (Democrat) 1907
- John I. Moore (Democrat, acting) 1907
- Xenophon Overton Pindall (Democrat, acting) 1907-1909
- George Washington Donaghey (Democrat) 1909-1913
- Joseph Taylor Robinson (Democrat) 1913
- William Kavanaugh Oldham (Democrat, acting) 1913
- Junius Marion Futrell (Democrat, acting) 1913
- George Washington Hays (Democrat) 1913-1917
- Charles Hillman Brough (Democrat) 1917-1921
- Thomas Chipman McRae (Democrat) 1921-1925
- Tom Jefferson Terral (Democrat) 1925-1927
- John Ellis Martineau (Democrat) 1927-1928
- Harvey Parnell (Democrat) 1928-1933
- Junius Marion Futrell (Democrat) 1933-1937
- Carl Edward Bailey (Democrat) 1937-1941
- Homer Martin Adkins (Democrat) 1941-1945
- Benjamin Travis Laney (Democrat) 1945-1949
- Sidney Sanders McMath (Democrat) 1949-1953
- Francis Cherry (Democrat) 1953-1955
- Orval Faubus[?] (Democrat) 1955-1967
- Winthrop Rockefeller[?] (Republican) 1967-1971
- Dale Bumpers[?] (Democrat) 1971-1975
- Bob Riley (Democrat, acting) 1975
- David Pryor[?] (Democrat) 1975-1979
- Joe Purcell (Democrat, acting) 1979
- Bill Clinton (Democrat) 1979-1981
- Frank D. White (Republican) 1981-1983
- Bill Clinton (Democrat) 1983-1992
- Jim Guy Tucker[?] (Democrat) 1992-1996
- Mike Huckabee[?] (Republican) 1996-present
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